1H-NMR and 13C-NMR Spectra of 1,2,2-trichloropropane The molecule has 3 different carbons, so the proton-spin decoupled 13C-NMR spectra will have 3 peaks. The molecule has only two different types of protons that are not coupled so the 1H-NMR will have two unsplit singlet signals. Off-Resonance-Decoupled 13C-NMR Spectrum of 1,2,2-trichloropropane Off-resonance-decoupled 13C-NMR Spectra of 1,2,2-trichloropropane. The CCl2 group appears as a singlet, the CH2Cl group appears as a triplet, and the CH3 group as a quartet. The off-resonance-decoupled carbon spectrum will show the spin-spin splitting between the carbon and the hydrogen it has attached to it. The N+1 rule applies so a carbon with 3 hydrogens on it will give rise to a quartet, while a carbon with only 1 hydrogen will have a doublet. Carbons with no hydrogens attached to them will have singlet signals. |
Organic Chemists from Industry and academics to Interact on Spectroscopy Techniques for Organic Compounds ie NMR, MASS, IR, UV Etc. Starters, Learners, advanced, all alike, contains content which is basic or advanced, by Dr Anthony Melvin Crasto, Worlddrugtracker, email me ........... amcrasto@gmail.com, call +91 9323115463 India skype amcrasto64
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