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Thursday, 3 December 2015

(S)-3-(benzyloxy)-2-methylpropanal

NMR INTERPRETATIONS FOR
(S)-3-(benzyloxy)-2-methylpropanal



VALUES

1H (400 MHz, d Chloroform)
1.15 (3H, d, J 7.0, CH3),
2.63 - 2.72 (1H, m),
3.66 (1H, dd, J 9.5, 5.5),
3.70 (1H, dd, J 9.5, 6.5),
4.54 (2H, s),
7.28-7.39 (5H, m),
9.74 (1H, d, J 1.5) 

13C (101 MHz, d Chloroform)
10.7, 46.8, 70.0, 73.3, 127.6, 127.7, 128.4, 137.8, 203.9.

REFERENCES
Zampella, A.; Sorgente, M.; D'Auria, M. V., Tetrahedron: Asymmetry, 2002, 13, 681 - 685 doi:10.1016/S0957-4166(02)00178-7
Harried, S. S.; Lee, C. P.; Yang, G.;Lee, T. I. H.; Myles, D. C., J. Org. Chem., 2003, 68, 6646 - 6660 doi:10.1021/jo034521r
Omura, K. ; Sharma, A. K.; Swern, D., J. Org. Chem., 1976, 41, 975 - 962 doi:10.1021/jo00868a012
SUPP INFO as entry 7 IN

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Malaita, Solomon Islands …









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http://graphics8.nytimes.com/images/2010/10/12/science/12saw_street/12saw_street-articleInline.jpg
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Gizo, on Ghizo Island, is the capital of the Solomon Islands’ far-flung Western Province, a paradise of coral cays, atolls, lagoons and volcanic islands east of Papua New Guinea where, on a rainy day in late July, crowds flocked to the local netball court for the opening of the inaugural Akuila Talasasa Arts Festival.


Motorised canoes lined up in Gizo Harbour near the daily marketplace. Picture: David May
Motorised canoes lined up in Gizo Harbour near the daily marketplace.










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Gizo Hotel, the best accommodation on Ghizo Island. Picture: David May
Vona Vona Lagoon and the beach at Zipolo Habu Resort on Lola Island. Picture: David May
Water views from Zipolo Habu Resort on Lola Island. Picture: David May


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DRUG APPROVALS BY DR ANTHONY MELVIN CRASTO
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