Trans-Cinnamamide , (2E)-3-Phenyl-2-propenamide

trans-Cinnamamide/(2E)-3-Phenyl-2-propenamide

Name	trans-Cinnamamide
Synonyms	(2E)-3-Phenyl-2-propenamide
Name in Chemical Abstracts	2-Propenamide, 3-phenyl-, (2E)-
CAS No	22031-64-7
EINECS No
Molecular formula	C9H9NO
Molecular mass	147.18
SMILES code	NC(=O)/C=C/c1ccccc1

1H NMR

1H-NMR: trans-Cinnamamide
250 MHz, DMSO-d6
delta [ppm]	mult.	atoms	assignment
6.61	d (JAB= 15.9)	1 H	C=CH-CO (2-H)
7.13	broad s	1 H	NH
7.2-7.6	m	7 H	CH (arom.) + NH + -CH=C (3-H)
7.42	d (JAB= 15.9)	1 H	-CH=C (3-H)
6.53	d	1 H	C=CH-CO (2-H, cinnamic acid)
7.82	d	1 H	-CH=C (3-H, cinnamic acid)
2.5	s		DMSO
3.33	s		O-CH3 (tBu-OMe)
1.19	s		C-CH3 (tBu-OMe)

13C-NMR

13C-NMR: trans-Cinnamamide
250 MHz, DMSO-d6
delta [ppm]	assignment
122.31	C2 (=CH-)
127.52	CH arom.
128.90	CH arom.
129.42	C4 (arom.)
134.86	C quart. arom.
139.16	C3 (-CH=C)
166.68	C1 (-C(=O)NH2)
38.5-40.5	DMSO-d6

IR

IR: trans-Cinnamamide
[KBr, T%, cm-1]
[cm-1]	assignment
3375, 3175	N-H valence
3084	aliph. C-H valence, =C-H
1665	C=O valence, carboxamide
1610	alkene C=C valence
1580, 1495	arom. C=C valence

Chromatogram

HPLC: crude product
column	Phenomenex Luna C18; particle diameter 3 µm, L= 150 mm, ID= 4.6 mm
column temperature	25 °C
injection	5 µL
mobile phase	5% MeCN / H2O (0.0059% CF3COOH), gradient to 95% MeCN / H2O (40 min), 10 min isocratic
flow	1.0 mL/min
detector (UV 220 nm)	percent concentration calculated from relative peak area

HPLC: pure product
column	Phenomenex Luna C18, particle diameter 3 µm, Länge 150 mm, Innendurchmesser 4.6 mm
column temperature	25 °C
injection	5 µL
mobile phase	5% MeCN/H2O (0.0059% CF3COOH), gradient to 95% MeCN/H2O (40 min), 10 min isocratic
flow	1.0 mL/min
detector (UV 220 nm)	percent concentration calculated from relative peak area

Name	trans-Cinnamamide
Synonyms	(2E)-3-Phenyl-2-propenamide
Name in Chemical Abstracts	2-Propenamide, 3-phenyl-, (2E)-
CAS No	22031-64-7
EINECS No
Molecular formula	C9H9NO
Molecular mass	147.18
SMILES code	NC(=O)/C=C/c1ccccc1

NH3

+

IR

IR: trans-Cinnamamide
[KBr, T%, cm-1]
[cm-1]	assignment
3375, 3175	N-H valence
3084	aliph. C-H valence, =C-H
1665	C=O valence, carboxamide
1610	alkene C=C valence
1580, 1495	arom. C=C valence

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Denpasar, bali, indonesia

1. Denpasar - Wikipedia, the free encyclopedia

   https://en.wikipedia.org/wiki/Denpasar

   
   

   Denpasar (Indonesian: Kota Denpasar, Indonesian pronunciation: [dənˈpasar]) is the capital and the most populous city of the Indonesian province of Bali.
   

   ‎Etymology - ‎History - ‎Geography - ‎Demography

   
   

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   Jagatnatha Temple Denpasar | Bali Places to Visit

   www.balisurfadvisor.com

   

   
   

   Denpasar market, Denpasar is the capital of Bali Province. The main street of Denpasar is Gajah Mada street where is the main shopping center, .

   
   

   A very giant Ogoh-ogoh at a cross junction in Denpasar

   
   

   

   
   

   

   
   

   

   A view from the Kumbasari Market

   
   

   

   
   

   

   
   

   

   
   

   
   

   

   

   

   
   

   

   
   

   
   

   PT (PERSERO) ANGKASA PURA I CABANG BANDARA NGURAH RAIGEDUNG WISTI SABHA LANTAI 3 BANDARA NGURAH RAIDENPASAR, BALI 80362

   Bali Airport (Ngurah Rai) Denpasar – Indonesia

   Bali Ngurah Rai International Airport, also known as Denpasar International Airport, is located in southern Bali, 13 km south of Denpasar. It is Indonesia’s third-busiest international airport.
   
   
   
   

   
   

   
   

   Bajak Laut Nasi Tempong & Seafood, Renon, Bali

    

   

   Sporting the growth of Denpasar residents' likes for Nasi Tempong, Bajak Laut Nasi Tempong & Seafood sets on a different kind of path by combining Nasi Tempong with the other well-known Bali's best: Seafood.
   

   

   Sets in the cozy neighborhood of Renon, Denpasar, Bajak Laut is the newest addition of restaurant openings in this area. From the down-to-earth food courts selling Ayam Goreng, Chinese food and Sup Kepala Ikan, to the more luxurious XO Suki & Cuisine, Ayucious, or the more established Bendega, Ikan Bakar Cianjur, and Hanamasa, Bajak Laut further marks Renon as a leading Denpasar's culinary destination.
   

   

   Though opened really close to the market leader Nasi Tempong Indra, that with its aggressive market expansion in 2012 opens two new branches around Renon area alone, Bajak Laut however has what Indra has not: various choices of seafood comprising of fishes, shellfish, crabs, and shrimps. Therefore market wise, Bajak Laut is aiming at a slightly different crowds: those who loves the spicy Nasi Tempong, and those who loves Seafood; especially those too tired to go through all the traffic madness at Simpang Siur to reach Jimbaran.
   (Or believes it's too touristy.)
   

   

   As the champion of this premise, Bajak Laut offers "Kepiting Asap ala Bajak Laut", which are crabs cooked in sweet and savory rubs, then grilled inside banana leaf wraps to enhance its aroma. The result is a treat not only delicious to the taste but also to the sight.
   

   

   Ingredients used for the rub is dominated with daun salam, or Indonesian bay leaves. For those familiar with gepuk; fried beef first marinated in spices and brown sugar, Kepiting Asap ala Bajak Laut has an almost identical seasoning.
   One portion of Kepiting Asap ala Bajak Laut consisting of two crabs weighing total of 5 ons (500 grams). At 120K they're good for two, while the 7 ons one costs 150K. For the 5 ons portion, the crab size is a bit small, hence eating them requires quite an effort.
   Nasi Tempong is a good example how a food originated from outside Bali could becomes a local hit. Originated from Banyuwangi, Nasi Tempong managed to get quite followers due to its main character of super spicy sambal. Nasi Tempong usually served as a package consisting of white rice, steamed vegetables, tahu, tempe, anemic salted fish, and super spicy sambal, and a main dish of either fried chicken, or other kind of proteins.
   While I'm not a die-hard spicy food fans, I found their Nasi Tempong quite palatable, especially since the stewed vegetables plus sambal that's the core of every Nasi Tempong dish, is like a staple food in Western Java where I grew up.
   Service is polite and attentive, though we found it's a bit hard to get attention from the waiters, except from the one stand by the front door. Beside of the seafood, the Nasi Tempong variations are sold around 12K to 45K,
   Starting December 2013 but don't know for how long, Bajak Laut Nasi Tempong & Seafood offers a special discount for their set menu, at 150K for 4 people, and 250K for 6 people.
   One annoying condition that we have to face as well, that even though the premise is fully airconed, people are allowed to smoke! And here in Denpasar, Bali, sadly it's the common case with many eating premises, and Bajak Laut is no exception. Therefore while their crab is quite delicious, until Bajak Laut separates its smoking and non-smoking section it poses health hazard to your youngsters. (byms)
   Bajak Laut Nasi Tempong & Seafood
   Jl. Cok Agung Tresna No.23, Renon, Denpasar, Bali
   (0361) 7984007

   
   

   
   

   
   

   
   

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7,7-dichlorobicyclo[4.1.0]heptane (7,7-dichloronorcarane

7,7-dichlorobicyclo[4.1.0]heptane (7,7-dichloronorcarane

+

NaOH,Pr3N

+

Synthesis of 7,7-dichlorobicyclo[4.1.0]heptane (7,7-dichloronorcarane) from cyclohexene

Reaction type:	addition to alkenes, elimination, cycloaddition
Substance classes:	alkene, carbene, chloroalkane
Techniques:	stirring with magnetic stir bar, adding dropwise with an addition funnel, distilling under reduced pressure, evaporating with rotary evaporator, shaking out, extracting, filtering, use of an ice cooling bath, heating with oil bath

http://kriemhild.uft.uni-bremen.de/nop/en/instructions/pdf/3005_en.pdf

Instruction (batch scale 100 mmol)
Equipment
100 mL three neck round bottom flask, reflux condenser, addition funnel with pressure
balance, heatable magnetic stirrer, magnetic stir bar, thermometer for inside of the flask,
separating funnel, destillation apparatus, rotary evaporator, oil bath, ice bath, vacuum pump
Substances
cyclohexene (bp 83 °C) 8.21 g (10.1 mL, 100 mmol)
chloroform (bp 61 °C) 48.0 g (32.7 mL, 400 mmol)
sodium hydroxide 16.0 g (400 mmol)
tri-n-propylamine (bp 156 °C) 0.14 g (0.19 mL, 1.0 mmol)
water 16 mL
ethanol (bp 78 °C) 1 mL
n-pentane (bp 36 °C) 120 mL
sodium sulfate for drying about 5 g
sodium chloride about 18 g
Reaction
Into a 100 mL three neck round bottom flask equipped with a reflux condenser addition
funnel, thermometer for measuring the inside temperature and magnetic stir bar, 8.21 g
(10.1 mL, 100 mmol) cyclohexene 0.14 g (0.19 mL, 1.0 mmol) tri-n-propylamine, 48.0 g
(32.7 mL, 400 mmol) chloroform and 1 mL ethanol is added. The mixture is cooled to 0 °C
with an ice bath, then under stirring and further cooling in the ice bath a solution of 16.0 g
(400 mmol) sodium hydroxide in 16 mL water is added through an addition funnel. The
mixture should be stirred vigourously during the next 20 minutes at 0 °C. After this time the
mixture is further stirred during 1 hour at room temperature and 3 hours at 50 °C.
Work up
Chloroform is evaporated with a rotary evaporator, then the residue is transferred with about
50 mL water and 30 mL n-pentane into a separating funnel. The organic phase is separated,
the aqueous phase is further extracted three times with 30 mL pentane. If an emulsion is
formed the aqueous phase is saturated with NaCl. The combined organic phases are dried over
sodium sulfate. The solution is filtered from sodium sulfate and the solvent is evaporated with
a rotary evaporator, yielding a nearly colourless liquid as crude product. The crude yield is
14.6 g. The crude product is distilled under reduced pressure.
Yield: 13.6 g (82.3 mmol, 82%), colourless liquid; bp 77 °C (11 hPa)

Operating scheme

Operating scheme

Equipment

Batch scale:

0.01 mol

0.1 mol

1 mol

Cyclohexene

	two-necked flask 10 mL			reflux condenser
	heatable magnetic stirrer with magnetic stir bar			thermometer
	graduated pipette			separating funnel
	microdistillation apparatus			rotary evaporator
	oil bath			ice bath
	vacuum pump

................




GC: pure productcolumnSE-54, L= 25 m, ID 0.32 mm, DF 0.25 µm (Macherey & Nagel)inletGerstel KAS, injector: 250°C, split injection 1:20, 0.15 µLcarrier gasN2, pre-column pressure 62 kPa, 1.04 mL/minoven80 °C (1 min), 10 °C/min --> 250 °C (30 min)detectorFID, 275 °Cintegrationpercent concentration calculated from relative peak area

1H-NMR: 7,7-Dichlorobicyclo[4.1.0]heptane
500 MHz, CDCl3
delta [ppm]	mult.	atoms	assignment
1.12-1.36	m	4 H	C4-H, C5-H
1.61-1.71	m	4 H	C3-H, C6-H
1.88-1.98	m	2 H	C1-H, C2-H
7.26	s	1 H	CHCl3

3C-NMR: 7,7-Dichlorobicyclo[4.1.0]heptane
125 MHz, CDCl3
delta [ppm]	assignment
18.9	C4, C5
20.2	C3, C6
25.8	C2, C1
67.4	C7
76.5-77.5	CDCl3

IR: 7,7-Dichlorobicyclo[4.1.0]heptane
[Film, T%, cm-1]
[cm-1]	assignment
2944, 2855	aliph. C-H valence
796	C-Cl valence

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............
Ubud, Bali, Indonesia.

Ubud, Bali, Indonesia.

Ubud - Wikipedia, the free encyclopedia

https://en.wikipedia.org/?title=Ubud

Ubud is a town on the Indonesian island of Bali in Ubud District, located amongst rice paddies and steep ravines in the central foothills of the Gianyar regency.

‎History - ‎Streets - ‎Buildings - ‎Economy

https://en.wikivoyage.org/wiki/Ubud

1. Ubud

   Town in Indonesia
2. The town of Ubud, in the uplands of Bali, Indonesia, is known as a center for traditional crafts and dance. The surrounding Ubud District’s rainforest and terraced rice paddies, dotted with Hindu temples and shrines, are among Bali’s most iconic landscapes. Ancient holy sites include the Tirta Empul temple complex, intricately carved Goa Gajah (“Elephant Cave”) and Gunung Kawi with its rock-cut shrines.
3. 
   
4. Weather: 27°C, Wind E at 14 km/h, 79% Humidity
5. Local time: Thursday 6:54 PM
6. Province: Bali
7. Getting there: 9 h 10 min flight. View flights
8. Points of interest
   View 5+ more

   

   Ubud Monkey Forest

   

   Neka Art Museum

   

   Blanco Renaissance Museum

   

   Agung Rai Museum of Art

   

   Puri Lukisan Museum

Bali: Avilla Opens Bale Udang Indonesian Restaurant in Ubud

Food and Beverage

Following the the success of its Bale Udang Mang Engking Indonesian restaurant in Kuta, Avilla Hospitality has opened a second Indonesian eatery in Ubud.

Bale Udang Engking Bali in Ubud. Photo Credit: Avilla Hospitality.

Set amid rice paddies with a view of the surrounding emerald green mountains, Bale Udang Engking Bali in Ubud is built almost entirely of bamboo atop a large fish pond.

Bale is Indonesian for an open-air structure made of bamboo.

More Than a Restaurant

Bale Udang Mang Engking at night. Photo Credit: Avilla Hospitality.

With its innovative design and magnificent setting, Bale Udang Mang Engking is more than a restaurant. There are also recreational facilities, a main hall, a souvenir shop, the list goes on.

Signature Dish

Yummy Indonesian cuisine at Bale Udang Mang Engking in Bali. Photo Credit: Avilla Hospitality.

Udang Bakar Madu, Sup Kelapa Udang, and Gurame Bumbu Cobek are among the yummy Indonesian dishes on the menu. Prawns are the signature ingredient in many of the dishes.

Bale Udang Mang Engking will offer 20% off ala carte menu items through the end of February 2014.

Where

Jl. Rya Goa Gajah, Banjar Teges Kanginan, Desa Peliatan, Ubud, Bali, Indonesia. Telephone: : +62 361 978 754. Website: Bale Udang Ubud.

Your Response Wanted!

Have you ever been to Bali? What was your most memorable experience? Would you recommend the island to others as a travel destination?

Please post your comment in the Comment Box below or on Facebook at the following link: Accidental Travel Writer on Facebook. And don't forget to LIKE us while you're there!

Travel Tips

ZUJI - Cheap Flights to Bali 

ZUJI Bali Travel Guide 

.

The Purist, Ubud, Bali, Indonesia | kacangbakar

kacangbakar.wordpress.com

Highly recommended food in Ubud (must try!): Babi Guling Bu Oka (BBQ pig). The food and environment are experience by itself. It is not open everyday, ...

How Ubud restored my faith in Bali |

theatlasheart.com

The one place that made me reevaluate my initial perception of Bali was Ubud. Ubud is what I was expecting Bali to be: a bit more laid back, hippie, ...

Air Route to Bali

Bali is a small island among the thousands of islands in the territory of Indonesia. The total area of Bali, about 5636.66 km2 with a population of not less than 4 million people. The island is a nature blessed with white sandy beaches, mountains with natural tropical forests, and lakes are very intriguing.

Bali has a main entrance through Ngurah Rai International Airport, located in southern Bali, 13 km south of Denpasar, the capital of Bali. It is Indonesia's third-busiest international airport.

Puri Saren Agung (Water Palace) in central Ubud

Goa Gajah originates from the 9th century

Gunung Kawi, Tampaksiring

Hot springs at Tirta Empul, Tampaksiring
 

Rice terraces near Ubud

Puram Dalem dance performance

Legong dance performance

Inside Ubud Market

Babi Guling is a very popular dish for Balinese as well as tourists, and you can find it at most traditional markets and at roadside eateries as wel

The quite remarkable Four Seasons Hotel in the Ayung Valley, near Ubud

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