NOESY NMR EXAMPLE.....(3S,5S)-10-(4-Nitrophenyl)-4,5a,6,7,8,10-hexahydro-5H-pyrrolo-[1,2-a]thieno[3,2-e][1,4]diazepin-2-one (18β)

NOESY experiment of diastereomer 18β (3S, 5S)
(3S,5S)-10-(4-Nitrophenyl)-4,5a,6,7,8,10-hexahydro-5H-pyrrolo-[1,2-a]thieno[3,2-e][1,4]diazepin-2-one (18β)

(3S,5S)-10-(4-Nitrophenyl)-4,5a,6,7,8,10-hexahydro-5H-pyrrolo-[1,2-a]thieno[3,2-e][1,4]diazepin-2-one (18β): Pale orange wax, 62%(104.0 mg).
[α]D29 = +8.8 (c = 1.0, MeOH).

1H NMR (CDCl3,300 MHz): δ = 1.83–1.92 (m, 2 H), 2.14–2.21 (m, 2 H), 2.90 (td, J= 8.7 Hz, 1 H), 3.41–3.47 (m, 1 H), 3.91 (t, J = 6.6 Hz, 1 H), 5.66(s, 1 H), 7.17–7.24 (m, 3 H), 7.44 (d, J = 8.7 Hz, 2 H), 8.18 (t, J =8.7 Hz, 2 H) ppm.

13C NMR (CDCl3, 75 MHz): δ = 24.88, 27.44,56.40, 63.70, 82.66, 111.10, 120.28, 124.26 (2 C), 125.37, 127.05 (2C), 135.23, 146.30, 147.97, 173.56 ppm.

LC–MS (ESI+): m/z =330.1 [M + H]+. HRMS: calcd. for C16H16N3O3S 330.0912 [M +
H]+; found 330.0914.

DOI: 10.1002/ejoc.201500943
Eur. J. Org. Chem. 2015, 7146–7153


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2-Methoxy-4-propylphenol

 

2-Methoxy-4-propylphenol

2-Methoxy-4-propylphenol
1H NMR (400 Mhz, CDCl3) δ (ppm): 6.83 (1H,d, J = 7.8 Hz), 6.68 (2H, d, J = 7.4 Hz), 5.47 (1H, s), 3.79 (3H, s), 2.52 (2H, t, J =7.6 Hz), 1.61 (2H, sext, J = 7.5 Hz) 0.94 (3H, t, J = 7.3 Hz).

13C NMR (100 MHz, CDCl3) δ (ppm) 146.4, 143.6,134.7, 121.0, 114.2, 111.1, 55.9, 37.8, 24.9, 13.8.

HRMS (ESI-TOF) m/z: [M + H]+ calculated for C10H15O2:167.1067; found: 167.1064.

DOI: 10.1021/acs.oprd.6b00441

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( E ) - 3 - (1 - Oxo - 1 - ( p - tolyl)propan - 2 - ylidene)isobenzofuran - 1(3H) - one

( E ) - 3 - (1 - O xo - 1 - ( p - tolyl)propan - 2 - ylidene)isobenzofuran - 1(3H) - one

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 Port louis,  mauritius

Port Louis

Capital of Mauritius

Port Louis is the capital city of Mauritius, located in the Port Louis District, the western part also lies in the Black River District. Port Louis is the country's economic, cultural, political centre and most populous city. Wikipedia

 


 

 


 


 

 
 

 

 

 

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