http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532014000100014&lng=en&nrm=iso&tlng=en
1,2-Bis(2-aminophenoxy)ethyl-N,N,N',N'-acetic acid methyl ester 4
Compound 3 (2.44 g, 0.01 mol) was dissolved in MeCN (10 mL), then (i-Pr)2NEt (6 mL) and methyl bromoacetate (3 mL) were added to the mixture with stirring. The reaction mixture was refluxed for 24 h. After the reaction, the mixture was cooled down, poured into EtOAc (20 mL), and filtered to remove the generated white solid. The combined EtOAc filtrates were concentrated in vacuo to give an oily solid, then adding a little methanol, white solid was generated, filtered, air dried and recrystallized in MeOH to give white solid 4. Yield 87%;
m.p. 94-95 ºC;
1H NMR (CDCl3, 400 MHz) δ 6.85 (m, 8H), 4.27 (s, 4H), 4.15 (s, 8H), 3.56 (s, 12H);
IRν/cm-1 3067, 2993, 2951, 2921, 2888, 1748, 1596, 1509, 1173, 742, 706.
m.p. 94-95 ºC;
1H NMR (CDCl3, 400 MHz) δ 6.85 (m, 8H), 4.27 (s, 4H), 4.15 (s, 8H), 3.56 (s, 12H);
IRν/cm-1 3067, 2993, 2951, 2921, 2888, 1748, 1596, 1509, 1173, 742, 706.
Journal of the Brazilian Chemical Society
Print version ISSN 0103-5053
J. Braz. Chem. Soc. vol.25 no.1 São Paulo Jan. 2014
http://dx.doi.org/10.5935/0103-5053.20130276
ARTICLE
Zhao Cheng; Bingqin Yang*; Meipan Yang; Binglin Zhang
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, College of Chemistry and Materials Science, Northwest University, 710069 Xi'an, China
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Vladivostok
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People taste traditional food to celebrate Nowruz Festival in Vladivostok, Russia, on March 22, 2014. Nowruz is a traditional festival which celebrates the ...
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