DR ANTHONY MELVIN CRASTO,WorldDrugTracker, helping millions, A 90 % paralysed man in action for you, I am suffering from transverse mylitis and bound to a wheel chair, With death on the horizon, nothing will not stop me except God................DR ANTHONY MELVIN CRASTO Ph.D ( ICT, Mumbai) , INDIA 25Yrs Exp. in the feld of Organic Chemistry,Working for GLENMARK GENERICS at Navi Mumbai, INDIA. Serving chemists around the world. Helping them with websites on Chemistry.Million hits on google, world acclamation from industry, academia, drug authorities for websites, blogs and educational contribution

Sunday, 7 December 2014

FLUORINE COMPD....13C NMR


Above is the aromatic region of the proton decoupled 13C NMR spectrum of alpha, alpha, alpha-trifluoro-p-tolualdehyde (the aldehyde peak is not shown). The assignments are given by the colors in the figure. Note the multiplicities in the 13C resonances due to the 1, 2 and 3 bond J coupling to 19F.








 
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DRUG APPROVALS BY DR ANTHONY MELVIN CRASTO

 
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DRUG APPROVALS BY DR ANTHONY MELVIN CRASTO


NORWAY\




Image result for NORWAY


Map of norway

















Norway: Oslo to Bergen by train










ALESUND




Stave church Heddal, Norway






Norway Bergen Tramway







At the top of Preikestolen with view over the Lysefjord, Norway 





Norway - Bergen Cityscape by AgiVega




13 C NMR ......CARBENE












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 ZANZIBAR, TANZANIA, AFRICA
 
 Zanzibar Banner.jpg

  1. A view over Stone Town from the sea































  2.   .
 

Zanzibar - Wikipedia, the free encyclopedia

https://en.wikipedia.org/?title=Zanzibar
Zanzibar (/ˈzænzɨbÉ‘r/) is a semi-autonomous part of Tanzania in East Africa. It is composed of the Zanzibar Archipelago in the Indian Ocean, 25–50 kilometres ...  

 

 
 



 


 

 































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    http://newdrugapprovals.org/

    DRUG APPROVALS BY DR ANTHONY MELVIN CRASTO











Saturday, 6 December 2014

HEAVY TRAFFIC ON YOUR FAVORITE BLOG........ORGANIC SPECTROSCOPY INTERNATIONAL







http://newdrugapprovals.org/
DRUG APPROVALS BY DR ANTHONY MELVIN CRASTO



7th Dec 2014

Time (UTC)IP AddressIP2Location
2014-12-06 06:15:51 PM81.205.159.42Amersfoort, Utrecht, Netherlands
2014-12-06 03:29:52 PM59.91.243.149Chandigarh, Chandigarh, India
2014-12-06 02:38:41 PM117.241.5.175Vijayawada, Andhra Pradesh, India
2014-12-06 11:28:07 AM195.154.209.237Paris, Ile-de-France, France
2014-12-06 11:25:29 AM195.154.217.154Paris, Ile-de-France, France
2014-12-06 11:23:03 AM59.184.49.229Mumbai, Maharashtra, India
2014-12-06 10:54:23 AM175.101.144.13Rajahmundry, Andhra Pradesh, India
2014-12-06 09:56:32 AM146.230.239.158Cape Town, Western Cape, South Africa
2014-12-06 09:30:15 AM146.230.239.158Cape Town, Western Cape, South Africa
2014-12-06 09:22:20 AM66.249.84.185Mountain View, California, United States
2014-12-06 09:20:35 AM173.252.112.112Menlo Park, California, United States
2014-12-06 09:20:34 AM173.252.112.118Menlo Park, California, United States
2014-12-06 08:52:46 AM66.249.83.185Mountain View, California, United States
2014-12-06 08:50:41 AM59.184.15.5Mumbai, Maharashtra, India
2014-12-06 07:39:26 AM78.128.151.173Pardubice, Pardubicky kraj, Czech Republic
2014-12-06 07:38:12 AM78.128.151.173Pardubice, Pardubicky kraj, Czech Republic
2014-12-06 07:33:39 AM78.128.151.173Pardubice, Pardubicky kraj, Czech Republic
2014-12-06 05:38:20 AM59.184.40.189Mumbai, Maharashtra, India
2014-12-05 07:59:13 PM87.72.203.37Albertslund, Hovedstaden, Denmark
2014-12-05 07:47:27 PM2.193.23.118Florence, Toscana, Italy
2014-12-05 07:12:43 PM14.139.57.34Chandigarh, Chandigarh, India
2014-12-05 04:39:51 PM79.98.75.185Mlada Vozice, Jihocesky kraj, Czech Republic
2014-12-05 04:32:56 PM209.15.21.139Atlanta, Georgia, United States
2014-12-05 02:25:35 PM59.184.43.244Mumbai, Maharashtra, India






6 TH DEC 2014

NOTE...BELOW IS MINE
2014-12-06 11:23:03 AM59.184.49.229Mumbai, Maharashtra, India

REST IS YOURS

Time (UTC)IP AddressIP2Location
2014-12-06 11:28:07 AM195.154.209.237Paris, Ile-de-France, France
2014-12-06 11:25:29 AM195.154.217.154Paris, Ile-de-France, France
2014-12-06 11:23:03 AM59.184.49.229Mumbai, Maharashtra, India
2014-12-06 10:54:23 AM175.101.144.13Rajahmundry, Andhra Pradesh, India
2014-12-06 09:56:32 AM146.230.239.158Cape Town, Western Cape, South Africa
2014-12-06 09:30:15 AM146.230.239.158Cape Town, Western Cape, South Africa
2014-12-06 09:22:20 AM66.249.84.185Mountain View, California, United States
2014-12-06 09:20:35 AM173.252.112.112Menlo Park, California, United States
2014-12-06 09:20:34 AM173.252.112.118Menlo Park, California, United States
2014-12-06 08:52:46 AM66.249.83.185Mountain View, California, United States
2014-12-06 08:50:41 AM59.184.15.5Mumbai, Maharashtra, India
2014-12-06 07:39:26 AM78.128.151.173Pardubice, Pardubicky kraj, Czech Republic
2014-12-06 07:38:12 AM78.128.151.173Pardubice, Pardubicky kraj, Czech Republic
2014-12-06 07:33:39 AM78.128.151.173Pardubice, Pardubicky kraj, Czech Republic
2014-12-06 05:38:20 AM59.184.40.189Mumbai, Maharashtra, India
2014-12-05 07:59:13 PM87.72.203.37Albertslund, Hovedstaden, Denmark
2014-12-05 07:47:27 PM2.193.23.118Florence, Toscana, Italy
2014-12-05 07:12:43 PM14.139.57.34Chandigarh, Chandigarh, India
2014-12-05 04:39:51 PM79.98.75.185Mlada Vozice, Jihocesky kraj, Czech Republic
2014-12-05 04:32:56 PM209.15.21.139Atlanta, Georgia, United States
2014-12-05 02:25:35 PM59.184.43.244Mumbai, Maharashtra, India








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MASS SPECTRUM.......ethyl 3-oxy-3-phenylpropanoate (ethyl benzoylacetate)

Structure: structure
IUPAC Name: ethyl 3-oxy-3-phenylpropanoate (ethyl benzoylacetate)


Mass Spectrum

Analysis: C11H123 MW = 192.21



The spectrum shows a small molecular ion peak, and a peak at m-45, suggesting the presence of an ethoxy group (-O-CH2CH3). The very minor peaks at 91 and 43 suggest that the molecule does not contain a benzyl unit or a methyl ketone. The base peak occurs at m/e = 105, and results from loss of a unit of m/e = 73, which is also observed. The molecular ion at 105 is characteristic of a carbonyl bonded directly to an aromatic ring.

MS Fragments:
fragments

The spectrum shows a small molecular ion peak, and a peak at m-45, suggesting the presence of an ethoxy group (-O-CH2CH3). The very minor peaks at 91 and 43 suggest that the molecule does not contain a benzyl unit or a methyl ketone. The base peak occurs at m/e = 105, and results from loss of a unit of m/e = 73, which is also observed. The molecular ion at 105 is characteristic of a carbonyl bonded directly to an aromatic ring.

3-pentanone (diethyl ketone)..MASS SPECTRUM

Structure: structure
IUPAC Name: 3-pentanone (diethyl ketone)

Analysis: C9H10O MW = 134.18


Mass Spectrum

The spectrum shows a moderate molecular ion peak, and a peak at m-15, strongly suggesting the presence of a labile methyl group. The base peak occurs at m/e = 91, which is highly suggestive of a benzyl fragment. The presence of an intense peak at m/e = 43 is also suggestive of the presence of a methyl ketone, which can fragment to form the acylium ion.

MS Fragments:
fragments

The spectrum shows a moderate molecular ion peak, and a peak at m-15, strongly suggesting the presence of a labile methyl group. The base peak occurs at m/e = 91, which is highly suggestive of a benzyl fragment, which rearranges to form the tropylium cation. The presence of an intense peak at m/e = 43 is also suggestive of the presence of a methyl ketone which can fragment to form the acylium ion.