.
7-Phenyl-6-heptyn-3-one.
The physical properties are as follows:
1H NMR (500 MHz, CDCl3) δ: 0.99 (t, J = 7.0 Hz, 3 H), 2.38 (q, J = 7.5 Hz, 2 H), 2.55–2.59 (m, 2 H), 2.62–2.65 (m, 2 H), 7.16–7.19 (m, 3 H), 7.26–7.29 (m, 2 H);
13C NMR (125 MHz, CDCl3) δ: 7.7, 14.1, 36.0, 41.2, 80.9, 88.7, 123.7, 127.7, 128.2, 131.6, 209.3;
IR (neat) cm-1: 3055, 2976, 2239, 1715, 1481, 1363;
GC-MS (Relative Intensity) m/z: 186 ([M+], 31), 171 (12), 157 (100), 128 (65), 115 (70), 102 (13), 89 (10).
Purity analysis data on distilled material are as follows: Anal. Calcd. for C13H14O: C, 83.83; H, 7.56. Found: C, 83.33; H, 7.58; HPLC > 99% area % purity at 254 nm detection (HPLC conditions, AgilentTM
20RBAX RX-SiL column (4.6 × 250 mm), 5 µM particle size; 0.70 mL/min
flow; eluent (hexanes/isopropanol = 98/2); product elutes at 5.42 min.
(HPLC conditions in submitter’s report: SupelcosilTM LC-PAH
C18 column (4.6 × 250 mm), 5 µM particle size; 0.75 mL/min flow; eluent
(hexanes/isopropanol = 99/1); product elutes at 5.2 min.) The sample was
prepared by dissolving 5 µL of the product in 5 mL of hexanes and the
injection volumes equal to 50 µL.
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Phi Phi Island from Don Mueang International Airport.
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7-Phenyl-6-heptyn-3-one.
The physical properties are as follows:
1H NMR (500 MHz, CDCl3) δ: 0.99 (t, J = 7.0 Hz, 3 H), 2.38 (q, J = 7.5 Hz, 2 H), 2.55–2.59 (m, 2 H), 2.62–2.65 (m, 2 H), 7.16–7.19 (m, 3 H), 7.26–7.29 (m, 2 H);
13C NMR (125 MHz, CDCl3) δ: 7.7, 14.1, 36.0, 41.2, 80.9, 88.7, 123.7, 127.7, 128.2, 131.6, 209.3;
IR (neat) cm-1: 3055, 2976, 2239, 1715, 1481, 1363;
GC-MS (Relative Intensity) m/z: 186 ([M+], 31), 171 (12), 157 (100), 128 (65), 115 (70), 102 (13), 89 (10).
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Phi Phi Island Thailand
Phi Phi Islands - Wikipedia, the free encyclopedia
en.wikipedia.org/wiki/Phi_Phi_Islands
The Phi Phi Islands (Thai:
หมู่เกาะพีพี, Thai pronunciation: [pʰīː pʰīː]) are located in Thailand,
between the large island of Phuket and the western Strait of ...
.
.
Thailand
is a big market these days for travelers from across the globe. The
rare exotic beaches, jungles and the ancient civilization and kingdom
built around happiness is a place of relaxation and wonder. Phi Phi
Islands are one of the most popular daytrips from the famous beach
peninsula of Phuket, but they can also be quiet and inviting places to
stay as well. The islands see the most foot traffic around noon till
5pm each day when day trip tours pour in from all sides. During this
time the tiny shops, little travel agencies and restaurants of all kinds
will be bustling with business. Its not too inconvenient for the island
dweller, because one can just as easily avoid the rush by enjoying a
nap or wandering out to one of the back beaches where the tourist boats
don’t pull up. For those who do enjoy crowds and parties there is a lot
going on during the daytime rush too. The island goes back and forth
between a vibrant party scene and a quiet tropical isle. The
hotels are mostly concentrated on the main island of the Phi Phi chain
which is called Ko Phi Phi Don Island. All have in common their great
location, not one of them is more than two minutes walking from the
island beaches. Also one won’t find the massive resort style buildings
here that exist in Phuket. Most hotels have a smaller campus with
bungalows and rooms never totaling more than 100. This doesn’t mean
infrastructure is lacking. There are restaurants, pools, private
balconies, coffee shops, gift shops and gardens. Outrigger, Arayaburi,
Holiday Inn, Zeavola and Phi Phi beach resort are among the best spots. Getting
to the island is done by ferry or speedboat. The general access points
are from Rassada Pier in Phuket or the pier just outside Krabi town. The
prices range from 350-1000 baht depending on the ferry chosen and the
time of year. It is a good policy only to buy the tickets you absolutely
need, don’t get talked into any deals or combo packages and know that
you can buy the same tickets on the dock, in tourist offices and in
stores, so shop around and you can find out who will give you the best
price. Speedboats are generally much higher in cost, but can be worth it
if you are looking to avoid crowds and get to the island as soon as
possible.
We
are a group of avid and discerning travelers enjoying real life trips,
quests and adventures. This is the place to come for everything one
needs to know before traveling. Our website delivers a vast range of
practical information related to traveling including travel tips, suggested itineraries and overall, practical travel knowledge.
.
Cheap great deal Phi Phi Hill Resort on Phi Phi Don 2011
Phi
Phi Hill Resort on Phi Phi Don 2011 Sorry been away..... dealing with
life 'n stuff!! It's high season again and Phi Phi Hill Resort has just
opened up for the next 6 months. Phi Phi Hill Resort closes every year
around May as the owner head back to Krabi, catch up with friends and
family and generally take it easy. High season comes round quick enough
and Phi Phi Hill Resort is busy for most of this time. If you are
looking for a quiet resort away from the main village, this could be the
place for you. If you are wanting to be close to a stunning beach with
coral, again Phi Phi Hill resort has that and if you want some of the
best views from Phi Phi Don over towards the Tonsai Cliffs or Phi Phi
Ley, this place ticks all the boxes. Check it out here; Phi Phi Hill Resort.
Prices are from 750 THb a night for 2 people sharing but this will be
their most basic room without aircon. However Phi Phi Hill Resort is
perched on the top of the Long Beach Headland so there are continual breezes. You can see the Phi Phi Hill Resort prices here.
Koh Phangan Full Moon Party Dates
Koh Phangan Full Moon Party Dates
As
with many types of traveller, everybody seems to want to know the dates
of the next Koh Phangan Full Moon Party. It's almost seems a chant, a
rhythmical demand for information about the next party that runs through
the conversations every few weeks. The Koh Phangan Full Moon Party
holds a strong and focal point for many people who are here to visit
Thailand but want to be where it's at. And why not, this party is the
biggest in Thailand, Biggest in South East Asia and one of the biggest
in the world. A blast, awesome, the best, unmissable, these are just a
few of the superlatives to describe it.
Koh Phangan Full Moon Party Dates 2012 see below
As
you get down to the half a kilometer wide beach you realize you have
stumbled on one of the best settings for a full moon party. The moon
rising and setting in front of you, 29 degrees warm sea, a flat line
horizon and thousands and thousands of party people...the drums the
music the vibe... party paradise.
Through
out the season on Phi Phi Island there is an exodus to Koh Phangan Full
Moon Party a few days before every Full Moon Party date. All the travel
businesses near Phi Phi Don Pier are busy selling the boat- bus- boat-
bus joint tickets.
The
need for accommodation is also another key aspect of organizing your
stay. Don't forget that most places insist that if you book ahead, and
this is definitely recommended, you must book a 5 night stay which is
not very accommodating. If you arrive there without accommodation you
will probably find a place to stay but it might be far from Haad Rin
beach (the party beach), badly expensive and of poor quality.... think
about it...,. the best places will be booked up ahead. So check out your
accommodation before you arrive. You can try places like Siam UK Travel and Tours on Phi Phi Island see them on facebook here. You can also try a great accommodation booking website like hotel-travel-phangan.com
Cheap food on Phi Phi Island
Cheap Hotel food on Phi Phi Don
http://cheaphotellondonhotels.blogspot.in/2013/03/cheap-food-on-phi-phi-island.html Most
hotels, resorts or guesthouses will offer an international menu at
least at breakfast where eggs are ubiquitous form of early morning food.
Where the menus get interesting is with the Thai lunches, Chinese
noodles and the full blown curries. Inexpensive or cheap food is a
matter of the wallet but I would always go for the freshly caught fish
as not only is it fresh that morning it will be way more than 70%
cheaper than you'd pay or the western capitals. Noodles, noodle soup are
good value and variations of fried rice can be sensational. More here
on Dining on Phi Phi Island
Cheap Market food on Phi Phi Don
Phi Phi Island market is near the pier on Phi Don Island.Just
behind the main street as you walk into to the village there is a
thriving market bazaar, selling the entire gamut of fish, meat and
vegetables that are common in all Thai cooking. Along side this are the
local curry houses where you can find all the local southern favourites
from Geng Som to Geng Pla Kem, salty fish and bar b q snapper. My
favourites are the fresh seafood curries and as long as you can handle
the spices, the fish heads and bones are an amazing culinary experience
worthy of more acclaim.
Wholesale prices for food on Phi Phi Island
Phi
Phi Don gets it's food from Phuket and Krabi by boat. This is itself
explains why food is more expensive as it needs to be handled on and off
the boats and the cost of the ferries makes it more expensive.The
market is the place to check out prices but haggling is difficult. If
you interested in bulk purchases it is better to do your shopping at the
talad (market) in Phuket and Krabi.
Cheap Accommodation Near the Market.
Ivory Phi Phi is right on the market itself. Hussin House is very simple and just off the main market near Moskito Diving. Phi Phi Guesthouse Marine House is next door to Hussin House.
Phi Phi Island from Don Mueang International Airport.
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