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Showing posts with label 2-pentanol. Show all posts
Showing posts with label 2-pentanol. Show all posts

Thursday, 4 December 2014

MASS SPECTRUM.......2-pentanol

Structure: structure
IUPAC Name: 2-pentanol

Analysis: C5H12O MW = 88.15




Mass Spectrum


The spectrum shows a small molecular ion and a small m-1 peak, suggesting the presence of an alcohol (it cannot be an aldehyde since there are no degrees of unsaturation). The m-15 peak represents loss of a methyl group and the m-17 is consistent with loss of a hydroxy radical. For an alcohol, the base peak is often formed by expulsion of an alkyl chain to give the simple oxonium ion R'CR''OH+; to generate the observed m/e = 45, R' must be CH3 and R' a H.






MS Fragments:
fragments

The spectrum shows a small molecular ion and a small peak resulting from loss of a hydrogen atom from the alcohol. Loss of a methyl group gives the m-15 peak and loss of hydroxy radical gives the secondary carbocation at m-17. The base peak, not surprisingly, is formed by expulsion of the alkyl chain to give the simple oxonium ion at m/e = 45.







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