Molbank 2013, 2013(2), M797; doi:10.3390/M797

Short Note

2-Chloro-7-methyl-3-({4-[(4-nitrophenoxy)methyl]-1H-1,2,3-triazol-1-yl}methyl)quinoline

Koduru Sri Shanthi Praveena ¹, Nandula Yadagiri Sreenivasa Murthy ² and Sarbani Pal ^1,* 

¹ MNR Degree & PG College, Kukatpally, Hyderabad-500085, A.P., India² Department of Chemistry, School of Engineering, Anurag Group of Institutions, Ranga Reddy District-501301, A.P., India

http://www.mdpi.com/1422-8599/2013/2/M797

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The title compound, 2-chloro-7-methyl-3-({4-[(4-nitrophenoxy)methyl]-1H-1,2,3-triazol-1-yl}methyl)quinoline was synthesized in one pot. The structure of the compound was fully characterized by IR, 1H and 13C-NMR, mass spectral analysis and elemental analysis.

 

Description of the compound 2: Off white solid.

Yield: 1.54 g, 94%.

M.p.: 175–177 °C.

Rf: 0.39 (Chloroform:Ethyl acetate = 3:1).

IR υmax (KBr, cm−1): 3151, 3118, 2924, 2852, 1594, 1496.0, 1340, 1264, 1230, 1111.

Mass (ES): m/z 410 (M+1, 100%).

1H-NMR (CDCl3, 400 MHz): δ 8.20 (d, J = 9.3 Hz, 2H), 7.94 (s, 1H), 7.80 (s, 2H), 7.66 (d, 1H, J = 8.3 Hz),

7.42 (d, 1H, J = 8.3 Hz), 7.07 (d, 2H, J = 9.3 Hz), 5.82 (s, 2H), 5.32 (s, 2H), 2.57 (s, 3H).

13C-NMR (CDCl3, 100 MHz): δ 163.0, 148.9, 147.9, 142.7, 142.4, 141.9, 140.8, 138.8, 137.0, 130.2,

127.4, 125.9, 125.3, 123.5, 114.9, 62.4, 51.5, 27.5.

Elemental analysis found C, 58.46; H, 3.79; N, 17.38. Calc. for C20H16ClN5O3; C, 58.61; H, 3.94; Cl,

8.65; N, 17.09; O, 11.71. 

 

ANDHRA FOOD