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Tuesday, 18 July 2017

(+)-Neomenthol

(+)-Neomenthol (3u) - 1H NMR (CDCl3)





(+)-Neomenthol (3u) [15] Yield: 0.0394g (0.2526 mmol, 92%); clear oil.

1H NMR (500 MHz, CDCl3): δ = 4.12 (m, 1H), 1.85 (dq, J = 2.4, 3.6, 13.8 Hz, 1H), 1.71 (m, 3H), 1.53 (m, 2H), 1.29 (dd, J = 3.0, 12.9 Hz, 1H), 1.14 (m, 3H), 0.98 (d, J = 6.6 Hz, 3H), 0.94 (d, J = 6.6 Hz, 3H), 0.89 (d, J = 6.6 Hz, 3H).


13C NMR (75 MHz, CDCl3): δ = 67.7, 47.9, 42.6, 35.1, 29.2, 25.8, 24.2, 22.3, 21.2, 20.7.


IR (ATR): 3427, 2947, 2916, 2869, 1712, 1456, 1367, 1242, 1153, 1026, 960, 937, 679 cm-1 .



[15] Dieskau, A. P.; Begouin, J.-M.; Plietker, B. Eur. J. Org. Chem. 2011, 5291–5296

1H AND 13C NMR PREDICT







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