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N - (benzyloxy) - 2,2,2 - trichloroacetamide
Access to the Pyrroloindoline Core via [3 + 2] Annulation as well as the Application in the Synthetic Approach to (±)-Minfiensine
Department of Pharmacology and
Pharmaceutical Sciences, School of Medicine, Collaborative Innovation
Center for Diagnosis and Treatment of Infectious Diseases, Tsinghua University, Beijing 100084, China
Org. Lett., Article ASAP
DOI: 10.1021/acs.orglett.5b03421
Publication Date (Web): January 8, 2016
Copyright © 2016 American Chemical Society
*E-mail: liaoxuebin@mail.tsinghua.edu.cn.
A
[3 + 2] formal cycloaddition reaction using aza-oxyallyl cation as a
synthetic synthon was developed to construct the pyrroloindololine core.
With this novel method, a variety of C3-substituted indoles were
readily converted into the corresponding pyrroloindoline analogues at
room temperature in the mixed solvents. To further demonstrate the
utility of this method, a synthetic approach to the total synthesis of
(±)-minfiensine was developed in quite concise fashion.
http://pubs.acs.org/doi/suppl/10.1021/acs.orglett.5b03421/suppl_file/ol5b03421_si_001.pdf
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Al-Qusayr
City in Syria
Al-Qusayr
is a city in western Syria, administratively part of the Homs
Governorate. It is located about 35 kilometers south of Homs and is
situated in a mountainous area overlooking Syria's border with ... Wikipedia
The ubiquitous yummy Kabab
This shot … well, a Syrian school girl.
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