DR ANTHONY MELVIN CRASTO,WorldDrugTracker, helping millions, A 90 % paralysed man in action for you, I am suffering from transverse mylitis and bound to a wheel chair, With death on the horizon, nothing will not stop me except God................DR ANTHONY MELVIN CRASTO Ph.D ( ICT, Mumbai) , INDIA 25Yrs Exp. in the feld of Organic Chemistry,Working for GLENMARK GENERICS at Navi Mumbai, INDIA. Serving chemists around the world. Helping them with websites on Chemistry.Million hits on google, world acclamation from industry, academia, drug authorities for websites, blogs and educational contribution
Showing posts with label Mom. Show all posts
Showing posts with label Mom. Show all posts

Saturday, 29 October 2016

2-bromocyclohexane-1,3-dione, Mom will teach you NMR

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Mom will teach you NMR,So easy


1H NMR (CDCl3, 300 MHz): δ 6.63(s, 1H), 2.61(t, J = 5.9 Hz, 4H), 2.03 (p, J = 5.9 2 Hz, 2H).




BLACK =1H NMR
RED = 13C NMR




1H NMR PREDICT






13C NMR PREDICT




Image result for MOM NMR





Image result for MOM NMR



COCK SAYS MOM CAN TEACH YOU NMR
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Friday, 6 May 2016

Substituted Isatins, mom will teach NMR







1H NMR CDCL3


13C NMR CDCL3


 










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09b37-misc2b027LIONEL MY SON
He was only in first standard in school when I was hit by a deadly one in a million spine stroke called acute transverse mylitis, it made me 90% paralysed and bound to a wheel chair, Now I keep him as my source of inspiration and helping millions, thanks to millions of my readers who keep me going and help me to keep my son happy





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La Maddalena, italy

Chilling at the white sandy beaches while enjoying a turquoise sky and the sound of a sea. That’s how many of us imagine perfect summer vibe. But what if I tell you, you don’t need to travel to Bahamas or Maldives to get what you want.
Sardinia, Italy and its destinations starting with Porto Cervo and ending with Cagliari have been always popular among tourists. However, charming rocky archipelago La Maddalena takes it to the next level. No wonder they call it “European Caribics”.
This National Park consists of 7 islands: La Maddalena, Caprera, Santa Maria, Spargi, Santo Stefano, Budelli and Razzoli; and many little islets. On the main island - La Maddalena you ll find the only town of the archipelago, carrying the same name. However a few villas can be found also on Caprera, Spargi and Santa Maria, and a hotel resort on Santo Stefano. La Maddalena offers plenty accommodation options from B&B to luxury resorts, even private villas or apartments. The best places for your stay are definitely on AIRBNB or you can try Subito.it if you speak Italian.
  
After taking a 20 minute sail by ferry from Palau to La Maddalena (around 50€ return ticket for car and passengers) you’ll find yourself at the centre of the city. It could be very busy and the traffic is really crazy, having almost no rules whatsoever. Narrow streets framed with oleanders, tiny coffeeshops and the aroma of the small port catches the attention of the visitor. But we came here to see those beautiful beaches, right?
Beaches
To visit a beach you’ll need a car or a motorbike, since many of them are not in a walking distance. All the beaches are gorgeous, but the prettiest is Bassa Trinita (don’t listen to Tripadvisor claiming the best one is Spalmatore!). It’s a bigger beach with soft sand, turquoise water. Capocchiad’u Purpu (or Testa del Polpo) is also lovely, but it’s more difficult to approach it. My personal favourite is definitely Spiaggia Carlotto, a small beach surrounded by rocky coastline at Cala Francese.
  
When you get bored on La Maddalena, you can easily visit Caprera. Those two islands are connected by bridge. The most popular beaches at Caprera are Il Relitto and I Due Mar,i however they can get crowded during the high season. But the location and surroundings are really exceptional. Cala Napoletana is claimed to be one of the prettiest beaches in the whole National Park but it is possible to approach it only from the boat just like Cala Coticcio that is being called “Tahiti”.
  
Staying at L’Arcipelago you must take a boat trip. You’ll visit the most beautiful beaches in the National Park that can be reached only by the sea. “Piscine Naturali” or natural pools are located on the Budelli island. There are 6 beaches on the Spargi island, all of them are beautiful with the most popular being Cala Corsara surrounded by tall cliffs – Pirates of Caribbean style.
 
Food
Italian cuisine is probably the most popular yet Sardinian is a bit different. While in La Maddalena, you have to try traditional dish called Ravioli Sardi. It’s ravioli filled with ricotta in tomato sauce with beef ragu and Sardinian sausage, soo delicious! But when you start to crave pizza, the answer is: Reginella (prosciutto crudo and heavy cream) or you can make up your own combination. What about bresaola and pecorino?
  
After a satisfying meal, it’s time for some sweet treat. During hot summer evenings, the only possibility is an ice-cream. The best is served in the small ice-cream store Bella Mia. Their offer differs every day. You can try interesting flavours like Ricotta with caramelized almonds, Mascarpone with figs or you can go for classics as vanilla, lemon and chocolate. Coconut, “bacio” and cherry cream are my favourites.
Hanging out & shopping
Is anything better than starting your day with a cup of coffee? I doubt that. Caffé Degli Artisti is an amazing place to enjoy your morning caffeine shot or even sweet breakfast. Delicious coffee and in store made pastry with a view at the lovely port.
In Italy, it is almost a tradition to start the evening in some “apero bar”. The coolest place for that is I Vitteloni. The bar offers small snacks like panini and their drink menu won’t disappoint you alongside with stylish interior.

  
The best idea how to spend your days is renting a boat or attending a boat trip to visit other islands in archipelago. When joining a boat tour you can get tired of the group sailing with you but the crew definitely knows the most beautiful and interesting spots. While renting a boat could give you more freedom you might not be sure where to go.
The little island has so many things to offer. Leaving it without buying a souvenir is impossible. Visit Veleria Il Ponente Store and shop their original & unique designs that are made of vintage sail. If you’re sailing/ yachting fan or you support sustainable, handmade fashion, you have to stop by.

Map of La Maddalena Italy
La Maddalena
Town in Italy
La Maddalena is a town and comune located on the island with the same name, in northern Sardinia, part of the province of Olbia-Tempio, Italy.Wikipedia














Monday, 11 January 2016

N - (benzyloxy) - 2,2,2 - trichloroacetamide taught by Mom, Aunt




MOM can teach you organic spectroscopy..............so easy


N - (benzyloxy) - 2,2,2 - trichloroacetamide


Access to the Pyrroloindoline Core via [3 + 2] Annulation as well as the Application in the Synthetic Approach to (±)-Minfiensine

Department of Pharmacology and Pharmaceutical Sciences, School of Medicine, Collaborative Innovation Center for Diagnosis and Treatment of Infectious Diseases, Tsinghua University, Beijing 100084, China
Org. Lett., Article ASAP
DOI: 10.1021/acs.orglett.5b03421
Publication Date (Web): January 8, 2016
Copyright © 2016 American Chemical Society


Abstract Image
A [3 + 2] formal cycloaddition reaction using aza-oxyallyl cation as a synthetic synthon was developed to construct the pyrroloindololine core. With this novel method, a variety of C3-substituted indoles were readily converted into the corresponding pyrroloindoline analogues at room temperature in the mixed solvents. To further demonstrate the utility of this method, a synthetic approach to the total synthesis of (±)-minfiensine was developed in quite concise fashion.

http://pubs.acs.org/doi/suppl/10.1021/acs.orglett.5b03421/suppl_file/ol5b03421_si_001.pdf





 TAKE A TOUR



Map of al qusayr syria
Al-Qusayr
City in Syria
Al-Qusayr is a city in western Syria, administratively part of the Homs Governorate. It is located about 35 kilometers south of Homs and is situated in a mountainous area overlooking Syria's border with ... Wikipedia


 

 

 
 

 

 
 

The ubiquitous yummy Kabab

This shot … well, a Syrian school girl.

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