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Monday 11 January 2016

N - (benzyloxy) - 2,2,2 - trichloroacetamide taught by Mom, Aunt




MOM can teach you organic spectroscopy..............so easy


N - (benzyloxy) - 2,2,2 - trichloroacetamide


Access to the Pyrroloindoline Core via [3 + 2] Annulation as well as the Application in the Synthetic Approach to (±)-Minfiensine

Department of Pharmacology and Pharmaceutical Sciences, School of Medicine, Collaborative Innovation Center for Diagnosis and Treatment of Infectious Diseases, Tsinghua University, Beijing 100084, China
Org. Lett., Article ASAP
DOI: 10.1021/acs.orglett.5b03421
Publication Date (Web): January 8, 2016
Copyright © 2016 American Chemical Society


Abstract Image
A [3 + 2] formal cycloaddition reaction using aza-oxyallyl cation as a synthetic synthon was developed to construct the pyrroloindololine core. With this novel method, a variety of C3-substituted indoles were readily converted into the corresponding pyrroloindoline analogues at room temperature in the mixed solvents. To further demonstrate the utility of this method, a synthetic approach to the total synthesis of (±)-minfiensine was developed in quite concise fashion.

http://pubs.acs.org/doi/suppl/10.1021/acs.orglett.5b03421/suppl_file/ol5b03421_si_001.pdf





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Map of al qusayr syria
Al-Qusayr
City in Syria
Al-Qusayr is a city in western Syria, administratively part of the Homs Governorate. It is located about 35 kilometers south of Homs and is situated in a mountainous area overlooking Syria's border with ... Wikipedia


 

 

 
 

 

 
 

The ubiquitous yummy Kabab

This shot … well, a Syrian school girl.

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