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Saturday 16 January 2016

Propylene carbonate

An efficient, metal- and solvent-free catalytic system was developed for the conversion of CO2and epoxides to the corresponding cyclic carbonates under mild conditions (T = 25–45 °C, 1 atm CO2) in high-to-excellent yields. The catalyst could be easily recycled, providing a more sustainable process for the chemical fixation of CO2.


Graphical abstract: An efficient metal- and solvent-free organocatalytic system for chemical fixation of CO2 into cyclic carbonates under mild conditions.
 Image result for Propylene carbonate
 Image result for Propylene carbonate


An efficient metal- and solvent-free organocatalytic system for chemical fixation of CO2 into cyclic carbonates under mild conditions

Lin Wang,a   Guangyou Zhang,b   Koichi Kodamaa and  Takuji Hirose*a  
*
Corresponding authors
a
Graduate School of Science and Engineering, Saitama University, 255 Shimo-Okubo, Sakura-ku, Saitama 338-8570, Japan 
E-mail: hirose@apc.saitama-u.ac.jp
b
School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China
Green Chem., 2016, Advance Article

DOI: 10.1039/C5GC02697K
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