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Friday, 2 January 2015

5,5-Dimethyl-2,2-di(pyridin-2-yl)hexahydropyrimidine


Colorless, Mp: 103 °C;
Molecular formula C16H20N4;
1H-NMR (250 MHz, CDCl3):
(ppm) 0.99 (s, 6H, CH3), 2.69 (br, 4H, CH2), 3.24 (br, 2H, NH), 7.10–8.20 (3m, 10H, Py–H),
13C-NMR
(62.5 MHz, CDCl3): (ppm) 24.83 (2CH3), 28.29 (C), 53.43 (2CH2), 75.82 (CN2) 122.09, 122.15 (p-CH
and m-CH), 136.70 (o-CH), 149.04 (m-CHN), 162.23 (i-C-Py).
Calcd. for C16H20N4: C, 71.61; H, 7.51;
N, 20.88. Found: C, 71.25; H, 7.31; N, 20.55).
[M+] = 270 m/z.
IR: 3390 cm−1N-H, 3080 cm−1C–H Py,2980–2700 cm−1C-H aliphatic.
Molbank 20152015(1), M838; doi:10.3390/M838
Short Note

5,5-Dimethyl-2,2-di(pyridin-2-yl)hexahydropyrimidine


Dr Ismail warad
warad@najah.edu

1 Department of Chemistry, AN-Najah National University P.O. Box 7, Nablus, Palestine
2 Department of Chemistry, College of Science, University of Hail, P.O. Box 2440, Hail, Saudi Arabia
3 Laboratoire LCM, Faculty of Science, University Mohammed Premier, Oujda-60000, Morocco
4 LCAE-URAC18, Faculty of Science, University Mohammed Premier, Oujda-60000, Morocco
Abstract: Novel 5,5-dimethyl-2,2-di(pyridin-2-yl)hexahydropyrimidine was synthesized in good yield by a one-pot condensation reaction of 2,2-dimethylpropane-1,3-diamine with di(pyridin-2-yl)methanoneusing dichloromethane as solvent at room temperature. The structure of the synthesized compound was assigned on the basis of its elemental analysis, UV-visible, 1H-NMR, 13C-NMR, IR, and mass spectral data.
http://www.mdpi.com/1422-8599/2015/1/M838



An-Najah National University is a vibrant hub of learning which nourishes science, knowledge and understanding. An-Najah offers undergraduate instruction in ...







Dr. Iz-Addin noted that the idea of the Bioequivalence Unit began in 1994 with the establishment of the Faculty of Pharmacy. Since that time, An-Najah has made considerable progress in the field of pharmacy, conducting a number of studies throughout the 1990s and founding The Drug Control and Biological and Chemical Analysis Center in 1999. Since its establishment, the Center has been working in cooperation with the Ministry of Health to offer drug analysis services. In order to build on its pharmaceutical research and services, the University launched a feasibility study in 2009, examining the possibility of founding a bioequivalence unit. Following the results of the study, in 2012, the University presented a formal application to the Ministry of Health to receive the first accreditation for a unit focusing on bioequivalence studies. 

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